硼氢化钠
电化学
双金属片
电催化剂
硼氢化
催化作用
化学
无机化学
纳米颗粒
玻璃碳
计时安培法
X射线光电子能谱
沉积(地质)
循环伏安法
材料科学
核化学
电极
化学工程
纳米技术
物理化学
有机化学
工程类
古生物学
沉积物
生物
作者
Şükriye Ulubay Karabiberoğlu,Zekerya Dursun
标识
DOI:10.1016/j.mseb.2022.116158
摘要
This work proposes Au-Pt nanoparticles decorated poly(p-aminophenol) (PAP) film on a glassy carbon electrode for direct electrochemical oxidation of sodium borohydride. The Au-Pt bimetallic surfaces were prepared with two electrodeposition procedures which are the simultaneous electro-deposition (1-Au-Pt/PAP/GCE) and the successive electro-deposition (2-Au-Pt/PAP/GCE) procedures. The catalysts were used for the investigation of borohydride electrochemical oxidation and compared catalytic activities by CV, RDEs and chronoamperometric techniques. AFM, SEM, XPS, XRD and CV were used to identify of the structural and morphological properties of the developed modified surfaces. The results of electrochemical measurements indicated that simultaneous electro-deposition of Au-Pt to the polymer structure significantly shifted negative oxidation potential and increases the current density of borohydride electrochemical oxidation. The exchange electron number of 1-Au-Pt/PAP/GC and 2-Au-Pt/PAP/GC electrodes were calculated as 7.8 and 6.7, respectively. This approves the strong tendency of the 1-Au-Pt/PAP catalyst toward effective direct electrochemical oxidation of NaBH4 in an alkaline medium.
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