High Power Factor and Mechanical Properties of Bi1-Xsbx Alloys Enabled by Redensification of Crystal Slabs

The low-cost Bi1-xSbx crystal has been considered the best low-temperature material for its high electrical properties, which also can generate high effective thermal conductivity, revealing a high potential in heat dissipation. But the weak mechanical strength hinders practical applications. Herein, we firstly grew the Bi1-xSbx crystal by the Bridgeman method, then cleaved the crystal into slabs with different sizes for hot-pressing. The obtained materials exhibited a high bending strength of 72 MPa, which is twofold that of Bi1-xSbx [001]-direction. Furthermore, the hot-pressed Bi1-xSbx samples show high electrical conductivities, being similar to those of the single crystals, resulting in the high record power factors of 78 μW·cm-1·K-2 @110 K and 38 μW·cm-1·K-2 @300 K among the hot-pressed polycrystalline Bi1-xSbx. This high electrical performance is beneficial to the applications of heat dissipation. Therefore, this work proves an effective way to simultaneously improve the mechanical and thermoelectric properties of Bi1-xSbx alloys.