Preparation of inexpensive S-doped porous carbons for high-performance supercapacitors

Low-cost sulfur-doped porous carbons were prepared through hard template method by using inexpensive colloidal SiO2 nanoparticles as template, glucose as carbon source, H2SO4 as pre‑carbonized reagent and sulfur source. The effects of H2SO4 and carbonization temperature on the microscopic morphology, the pore structure and the specific surface area of porous carbons were explored through multiple characterization methods. The capacitive performance of porous carbons was investigated by multiple electrochemical methods. It was found that the pore structure, specific surface area and the content of sulfur element of carbon are highly dependent on the carbonization temperature. The sulfur-doped porous carbon SPC-900 has much larger surface area and larger pore volume, and thus much better capacitive performance than un-doped PC-900, indicating that H2SO4 can increase the surface area and the pore volume during the preparation process. SPC-900 offers the advantages of lower cost, larger pore size, higher pore volume, better capacitive performance and better rate performance compared to expensive mesoporous carbon CMK-3. In the three-electrode system, the specific capacitance of SPC-900 can reach 363 F g−1, whereas that of PC-900 is only 164 F g−1 at a current density of 0.5 A g−1. The double layer capacitance (EDLC) and pseudocapacitance can both be increased by the sulfur element, according to the capacitive contribution study. Additionally, the SPC-900 can maintain its initial specific capacitance of 98.1 % for 10,000 cycles at a current density of 0.5 A g−1, demonstrating both its high cycling performance and potential for practical applications.