双金属片
过电位
析氧
电化学
电催化剂
钴
镍
材料科学
化学工程
金属有机骨架
分解水
无机化学
化学
催化作用
金属
电极
冶金
有机化学
物理化学
吸附
工程类
光催化
作者
Syed Shaheen Shah,Ahmed Albadrani,Mohammed Fettouhi,Md. Abdul Aziz,Aasif Helal
标识
DOI:10.1002/asia.202301039
摘要
In the realm of renewable energy technologies, the development of efficient and durable electrocatalysts is paramount, especially for applications like electrochemical water splitting. This research focuses on synthesizing a novel bimetallic metal-organic framework (BMMOF11) using earth-abundant elements, cobalt (Co) and cadmium (Cd). BMMOF11 showcases a distinctive structure with distorted octahedral chains of CoO and CdO, linked by benzene tricarboxylic acid (BTC). Our study primarily investigates the electrocatalytic efficiency of BMMOF11, particularly in water oxidation reactions. For practical analysis, BMMOF11 was anchored onto nickel foam, forming BMMOF11/NF, to evaluate its electrocatalytic properties. Electrochemical testing revealed that BMMOF11/NF begins water oxidation at an onset potential of 1.62 V versus RHE, demonstrating high activity with a lower overpotential of 0.4 V to achieve a current density of 10 mA/cm
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