Visible‐Light‐Mediated Vinyl‐Thiophosphate Formation Via Three‐Component Denitrative Cross‐Coupling Reaction

Abstract A three‐component denitrative cross‐coupling reaction mediated by visible light has been developed. Various 2‐arylvinyl thiophosphate compounds were synthesized with moderate‐to‐good yields using cheap, nontoxic, nonvolatile, and non‐hygroscopic elemental sulfur (S 8 ) as the raw material. These transformations allow the direct formation of C−S and S−P bonds without metal catalyst via a one‐pot procedure.