铀
聚丙烯腈
吸附
海水
萃取(化学)
化学
废水
核化学
化学工程
材料科学
色谱法
有机化学
冶金
废物管理
聚合物
地质学
工程类
海洋学
作者
Yiyang Zeng,Sheng Liu,Jicheng Xu,Zhang Ai,Yuxin Song,Long Yang,Ailin Pu,Yuran Ni,Fangting Chi
标识
DOI:10.1016/j.jece.2021.106490
摘要
With the vigorous development of nuclear power and the shortage of terrestrial uranium resources, the extraction uranium from seawater is extremely attractive for human development. Herein, we first report ZIF-8 in-situ growth on amidoximerized polyacrylonitrile (PAO) porous materials. The porous material is a small sphere with certain mechanical strength synthesized by solvent-induced phase separation method. Because ZIF-8 nanocrystals are well-formed and evenly distributed within the PAO beads, ZIF-8/PAO has a high specific surface area (386 m2 g-1) and rich pore structure. At adsorption experiment, the highest adsorption capacity of ZIF-8/PAO reached 803 mg g-1 at pH = 4. Furthermore, competitive adsorption experiment and simulated seawater test was studied. The selectivity for uranium was excellent (Kd = 1.7 × 105 mL g-1) and uranium adsorption rate reached 99% at 3 ug L-1. XPS analysis shows that U(VI) is chelated by imidazole-N atoms and amidoxime groups in ZIF-8/PAO. Therefore, ZIF-8/PAO can be considered a highly promising adsorbent for uranium extraction from wastewater and seawater.
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