过电位
电催化剂
电解质
电解
阳极
无机化学
氢
兴奋剂
化学
电解水
过氧化氢
极化(电化学)
氧气
催化作用
材料科学
电化学
电极
物理化学
有机化学
光电子学
作者
Junying He,Weixin Chen,Hongmei Gao,Yuxiang Chen,Ling Zhou,Yuqin Zou,Ru Chen,Tao Li,Xia Lu,Shuangyin Wang
出处
期刊:Chem catalysis
[Elsevier]
日期:2022-03-01
卷期号:2 (3): 578-594
被引量:23
标识
DOI:10.1016/j.checat.2022.01.012
摘要
Solid polymer electrolyzer (SPE), which directly uses pure water as electrolyte, holds great promise for green hydrogen production, yet developing a durable and active electrocatalyst for a proton-rich anode remains a bottleneck issue owing to the high catalyst dissolution under polarization potential. Here, proton and electron co-doping was employed to construct an Ru-O-H···O bond within RuO2 lattice, and the hydrogen binding modes not only engineered the electronic interaction between Ru and O atoms but also formed a hydrogen bond, which was demonstrated to be an effective way to increase the electrocatalytic activity and stabilize the lattice oxygen. The intrinsic activity of representative 75-H-RuO2 loaded on a glassy carbon electrode was almost ten times that of the pristine one, only requiring an overpotential of 200 mV (@10 mA cm−2). Moreover, it demonstrated ideal stability (@0.5 A cm−2) in the SPE device.
科研通智能强力驱动
Strongly Powered by AbleSci AI