表面张力
热力学
表面能
极地的
分子
吉布斯等温线
摩尔体积
相(物质)
化学
体积分数
标准摩尔熵
摩尔分数
氢键
化学极性
材料科学
物理化学
吉布斯自由能
有机化学
物理
天文
作者
Yong Zhao,Jing Zhu,Shengkang Wang,Yanjiao Chang,Weiwei Liu
标识
DOI:10.1016/j.physb.2022.414178
摘要
A new thermodynamic model equation of Vapor-Liquid surface tension γ is derived, γAm=Φ(V)(E(L)−E(V))−TΔS; where Am is the molar surface area, E(L) and E(V) are the molar cohesive energy of liquid phase and vapor phase correspondingly, Φ(V) the mean volume fraction exposed to vapor phase of a surface molecule, ΔS the excess surface entropy. Φ(V) is a function of (E(L)− E(V))/nsRT, ns denotes the segment number in a chain molecule, Φ(V) increases slowly with elevating temperature T. This model has been verified for surface tension estimation of simple liquids, organic liquids (non-polar, polar and hydrogen-bonding) and metallic liquids at various temperatures with successful results.
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