Covalent organic frameworks for applications in lithium batteries

Abstract With the stone energy increasingly dried up and the environment polluted severely, developing renewable clean energy is already in extreme urgency. Exploiting new energy storage and transformation systems has progressively become the focal point in the energy research field. Covalent organic frameworks (COFs) have attracted extensive attention as a new kind of crosslinked polymers owing to the high crystallinity, excellent porosity, and favorable stability. The last decade has witnessed the great progress in crystalline COFs for the application in various arenas. The tailor‐made functional skeleton together with well‐defined periodical alignment has endowed COFs with enormous potential in lithium batteries. In this review, we initially illustrated the design principle of COFs for the application in lithium batteries. Furthermore, we made a comprehensive summary of the fast‐developing COFs field in terms of lithium batteries, including lithium ion and lithium sulfur batteries. Finally, we discussed the remaining challenges and perspectives in this area and also proposed several possible future directions of development for lithium batteries. It is expected that this short review would contribute to the development of COFs materials in energy‐related applications.