咪唑
海绵
吡咯
化学
立体化学
广谱
氧化磷酸化
组合化学
有机化学
生物
生物化学
植物
作者
Zhiqiang Ma,Wang Xiao,Yuyong Ma,Chuo Chen
标识
DOI:10.1002/anie.201600007
摘要
Abstract Axinellamines A and B are broad‐spectrum antibacterial pyrrole–imidazole alkaloids that have a complex polycyclic skeleton. A new asymmetric synthesis of these marine sponge metabolites is described herein, featuring an oxidative rearrangement and an anchimeric chlorination reaction.
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