Proton exchange memb rane fuel cell has been considered one of the next generation power source for electric vehicles due to high power density and low emissions. TiO₂/Nafion composite was prepared by the in-situ sol-gel method. The electrochemical characteristics of the TiO₂-Nafion composite membrane were evaluated by current-voltage and impedance of the membrane eletrode assembly in a single Proton exchange membrane fuel cell (PEMFC).