催化作用
丁烷
钴
燃烧
化学
催化燃烧
ZSM-5型
沸石
无机化学
化学工程
有机化学
工程类
作者
Wei Zhao,Shanshan Ruan,Shen‐En Qian,Bo Feng,Chengcheng Ao,Lei Wang,Fuyi Liu,Peng Zhang
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2020-09-21
卷期号:34 (10): 12880-12890
被引量:20
标识
DOI:10.1021/acs.energyfuels.0c02717
摘要
Catalytic combustion has become a promising technology to address the accelerating volatile organic compounds (VOCs) emissions. In this work, cobalt modified ZSM-5 zeolite catalysts (3–18 wt % Co) were prepared to investigate the combustion of n-butane (one typical model component of VOCs). The performances of catalysts were evaluated by conducting experiments in a flow tube reactor. XRD, BET, FT-IR, and XPS were also utilized to characterize their physicochemical properties. A significant enhancement of the catalytic activity was demonstrated in terms of the cobalt supported over ZSM-5, with an optimal cobalt loading of 7 wt %. The excellent catalytic activity of 7 wt % Co-ZSM-5 is mainly attributed to a higher concentration of active surface Co3+ species. Furthermore, DFT calculations indicated that the role of Co can enhance the activity by decreasing the activation barriers for C–H bond cleavage. In addition, the primary reaction mechanism of n-butane combustion on Co-ZSM-5 was also revealed.
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