热分解
分解
经验模型
矿物油
热的
动能
热力学
石油工程
材料科学
计算机科学
化学
工程类
模拟
物理
冶金
量子力学
有机化学
作者
V. G. M. Cruz,André L.H. Costa,Márcio L.L. Paredes
标识
DOI:10.1590/0104-6632.20150323s00003531
摘要
AbstractDissolved gas analysis (DGA) has been applied for decades as the main predictive maintenance technique for diagnosing incipient faults in power transformers since the decomposition of the mineral insulating oil (MIO) produces gases that remain dissolved in the liquid phase. Nevertheless, the most known diagnostic methods are based on findings of simplified thermodynamic and compositional models for the thermal decomposition of MIO, in addition to empirical data. The simulation results obtained from these models do not satisfactorily reproduce the empirical data. This paper proposes a flexible thermodynamic model enhanced with a kinetic approach and selects, among four compositional models, the one offering the best performance for the simulation of thermal decomposition of MIO. The simulation results obtained from the proposed model showed better adequacy to reported data than the results obtained from the classical models. The proposed models may be applied in the development of a phenomenologically-based diagnostic method.
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