材料科学
腐蚀
氧化钇稳定氧化锆
热障涂层
陶瓷
扩散
相(物质)
热稳定性
铝
硅酸盐
热膨胀
复合材料
化学工程
立方氧化锆
冶金
工程类
有机化学
化学
物理
热力学
作者
Huanjie Fang,Weize Wang,Jibo Huang,Yuanjun Li,Dongdong Ye
标识
DOI:10.1016/j.corsci.2020.109230
摘要
In this study, corrosion behavior of Yb2O3-Y2O3 co-stabilized ZrO2 (YbYSZ) was systematically investigated under CMAS melt attack. The result was found that YbYSZ exhibited a better CMAS resistance than yttria stabilized zirconia (YSZ), which was attributed to the excellent phase stability. The degradation of grain caused by CMAS attack was greatly related to the diffusion rate of element substantially. Yb3+ exhibited a low diffusion rate contributing to good phase stability during corrosion. A corresponding first-principles calculation further confirmed this conclusion. Besides, YbYSZ showed a higher thermal expansion coefficient and lower thermal conductivity as compared with YSZ counterpart.
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