化学
二羟基化
吲哚试验
氧化还原
电化学
调解人
组合化学
羟基化
有机化学
电极
生物
对映选择合成
内分泌学
物理化学
催化作用
酶
作者
Ju Wu,Régis Guillot,Cyrille Kouklovsky,Guillaume Vincent
标识
DOI:10.1002/adsc.202000158
摘要
Abstract We describe a simple and sustainable MgBr 2 ‐mediated electrochemical dearomative dihydroxylation and hydroxycyclization reactions of indoles with water. MgBr 2 is used in substoichiometric amount and acts as an electrolyte and potentially as a redox mediator to indirectly oxidize the indole nucleus into a bromonium ion which is involved in the aforementioned reactions. magnified image
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