An Organic–Inorganic Hybrid Electrolyte as a Cathode Interlayer for Efficient Organic Solar Cells

Abstract An organic–inorganic hybrid electrolyte based on a cyclic Ti‐oxo cluster as the inorganic core and naphthalene‐based organic ammonium bromide salts as the electrolyte was developed with easy synthesis and low cost. The new hybrid electrolyte exhibits excellent solubility in methanol, aligned work function, good conductivity, and amorphous state in thin film, enabling its successful application as a cathode interlayer in organic solar cells with a high power conversion efficiency of 17.19 %. This work demonstrates that the hybrid electrolytes are a new kind of semiconductor, exhibiting promising applications in organic electronics.