材料科学
介孔材料
碳化
催化作用
碳纤维
化学工程
纳米颗粒
壳体(结构)
纳米技术
介孔二氧化硅
复合材料
化学
有机化学
复合数
扫描电子显微镜
工程类
作者
Shijun Liu,Yanlong Qi,Long Cui,Quanquan Dai,Shangjing Zeng,Chenxi Bai
标识
DOI:10.1016/j.apsusc.2019.07.047
摘要
Core-shell materials with tunable morphology have attracted fantastic attention in practical application and scientific research. Among them, yolk-shell structured materials with mesoporous shell are considered a promising framework for catalyst support, protecting active sites from aggregation or lossing. Compared with traditional synthesis method, we report a facile strategy for preparation of functional yolk-shell materials without selective etching of the core or template. 3-Aminophenol formaldehyde resin (3-AFR) is used as the core and carbon source. The modified 3-AFR spheres are coated by mesoporous silica and silver is introduced simultaneously, obtaining yolk-shell polymer-silica composites. Then the silver doped composites are carbonized and reduced in H2/Ar atmosphere. Particularly, the final products prepared through different pre-treatments show various morphologies and the obtained materials supporting well dispersed silver nanoparticles exhibit excellent catalytic activity for 4-nitrophenol (4-NP) reduction under room temperature with conversion of >98%, which may be attributed to well dispersed Ag nanoparticles and mesoporous silica shell. This strategy may be applicable to various yolk-shell materials with assistance of pretreatment, avoiding selective removal of core or template.
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