荧光粉
分析化学(期刊)
钨酸盐
扫描电子显微镜
傅里叶变换红外光谱
材料科学
发射光谱
粉末衍射
X射线光电子能谱
发光
离子
化学
谱线
结晶学
光学
光电子学
核磁共振
物理
冶金
天文
有机化学
复合材料
色谱法
作者
S. Sailaja,S. J. Dhoble,C. Nageswara Raju,B. Sudhakar Reddy
标识
DOI:10.1016/j.physb.2011.09.133
摘要
5 mol% of Pr3+ and Tm3+ ions activated calcium gadolinium tungstate (Ca2Gd2W3O14) phosphors were synthesized by traditional solid state reaction method. Crystalline phase structure was identified from the X-ray diffraction (XRD) profiles. From the scanning electron microscopy (SEM) images, we have observed the agglomeration of the particles, and average grain size is around 40–300 nm. Using the energy dispersive X-ray analysis (EDAX) and Fourier transform infrared (FTIR) spectra, identified the elements and functional groups present in the prepared phosphors. The emission spectrum of Pr3+: Ca2Gd2W3O14 powder phosphors have shown an intense red emission at 615 nm with the excitation wavelength λexci=450 nm and thus these red color emitting powder phosphors are used as one of the components in the preparation of WLEDs. The excitation spectrum of Tm3+: Ca2Gd2W3O14 powder phosphor has shown a ligand to metal charge transfer (W–O) band (LMCT) within the WO42− group. Emission spectrum of Tm3+: Ca2Gd2W3O14 phosphors have shown blue emissions at 453 nm (1D2→3F4).
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