发光
分析化学(期刊)
离子
镱
兴奋剂
原子物理学
材料科学
物理
化学
光电子学
色谱法
量子力学
作者
Д. В. Поминова,V. Yu. Proydakova,Igor Romanishkin,Pavel V. Grachev,S. V. Kuznetsov,Anastasia V. Ryabova
摘要
Study of energy transfer processes between the rare earth ions in NaGdF4 nanoparticles tri-doped with rare earth ions Yb3+, Er3+ and Ho3+ or Tm3+ was carried out. The luminescence spectra in short-wave infrared and visible ranges were investigated. It was shown that Er3+ → Ho3+ energy transfer leads to Ho3+ luminescence increase. Both Er3+ and Ho3+ luminescence peaks were observed in short-wave infrared range. For Er3+ and Tm3+ co-doped nanoparticles it was hard to separate luminescence peaks in SWIR. However, both Er3+ and Tm3+ luminescence peaks were observed in visible range. We attribute this effects to Tm3+ → Er3+ energy transfer which occurs due to overlap of Er3+ and Tm3+ luminescence bands in short-wave infrared range which leads to Tm3+ luminescence decrease. This hypothesis was confirmed by study of β-NaGdF4 tri-doped with Yb3+, Er3+ and Tm3+ luminescence spectra during heating. The intensity of Tm3+ luminescence increased during heating due to non-resonant nature of Yb3+ →Tm3+ energy transfer and the shape of spectra changed.
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