Crystal engineering of a new platform of hybrid ultramicroporous materials and their C 2 H 2 /CO 2 separation properties

outlet purities of 99.92% and 99.66%, respectively. This study introduces the use of diamine chelating ligands in HUMs for gas separations through two parent sorbents that are prototypal for families of related materials, one of which, SOFOUR-2-Zn, uses the earth-friendly sulfate anion as a pillar.