化学
罗丹明B
荧光
配位聚合物
光催化
发光
亚甲蓝
水溶液
降级(电信)
猝灭(荧光)
反应速率常数
光化学
核化学
聚合物
罗丹明
物理化学
有机化学
催化作用
动力学
电信
光电子学
量子力学
计算机科学
物理
出处
期刊:Polyhedron
[Elsevier]
日期:2022-12-01
卷期号:228: 116182-116182
被引量:3
标识
DOI:10.1016/j.poly.2022.116182
摘要
A stable 2D Co coordination polymer [Co(DCB)(BIMBP)]n (1) was advisably designed and synthesized (H2DCB and BIMBP are 1,1′-di(p-carbonylbenzyl)-2,2′-biimidazoline and 4,4′-bis(imidazol-1-ylmethyl)biphenyl). Profiting by the excellent luminescence performance and high stability in water, complex 1 is a latent multi-functional fluorescent probe toward Fe3+, Cr2O72− and CrO42−, and nitrofurantoin (NFT) in aqueous medium. The quenching constant (KSV) values of complex 1 are 1.56 × 104 M−1 for Fe3+, 1.45 × 104 M−1 for Cr2O72−, 1.19 × 104 M−1 for CrO42−, and 4.80 × 103 M−1 for NFT, respectively. Furthermore, complex 1 is an effective and stable photocatalyst and displays outstanding photocatalytic degradation of Rhodamine B (RhB) and methylene blue (MB) in water solution. The maximum degradation rate can reach 91.3 % for MB and 90.6 % for RhB in 80 min.
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