材料科学
复合材料
催化作用
热解
碳纤维
制作
硅
甲醛
碳化硅
苯酚
酚醛树脂
复合数
化学工程
有机化学
冶金
替代医学
化学
病理
工程类
医学
摘要
Compression moulding of short carbon fiber and resin,liquid resin impregnation and pyrolysis was included in C/C-SiC composites fabrication.Firstly,the analysis on graphitization shows carbon-silicon reaction enhanced Si activation to B and its graphitization rises from 87.9% to 97.3%.Investigation of morphologies and gradients shows graphitization occurred with carbon-silicon reaction.SiC shows uniform distribution inside materials.Secondly,boron-catalytic graphitization is discussed.With mass fractions of boracic formaldehyde-phenol resin,decreased from 69.9% to 46.3%,the graphitization degrees reduce from 91.6% to 70.4%.Finally,catalytic graphitization mechanism of Si is put forward.As contents of Si rises from 0 to 6.3%,graphitization degree of composites rises from 78.1% to 90.7%.
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