Controllable Reconstruction of β-Bi2O3/Bi2O2CO3 Composite for Highly Efficient and Durable Electrochemical CO2 Conversion

The uncontrollable electrochemical reduction reconstruction, leading to the destruction of well-defined structure and subsequent low durability, is the main obstacle to the catalytic performance of Bi-based composites toward electrochemical CO2 reduction reaction (eCO2RR). Herein, we address this issue through construction of a novel β-Bi2O3/Bi2O2CO3 composite, which can resist the reduction reconstruction of Bi-based materials to metallic Bi during the eCO2RR process by modulating a more alkaline microenvironment that facilitates the formation of new Bi–O bonds. The synergistic interactions and directional electron transfer between the β-Bi2O3 and Bi2O2CO3 components, together with the stable composite structure, result in its superior activity and selectivity for formate production with high faradaic efficiencies (FEs) over 94% from −0.7 to −1.1 V, and remarkable durability with maintenance of 80% FE after continuous electrocatalysis of 720 h. This work sheds new light on designing advanced high-performance nanomaterials toward eCO2RR and other practical applications.