Decreased Accumulation of SnO2 Particles Results from Sodium Citrate Dispersant Assisted Chemical Bath Deposition for High Quality Perovskite Solar Cells

Electron transport layer (ETL) is a crucial part for perovskite solar cells (PSCs). However, leakage current and oxygen vacancies result from little pores grown from sol‐gel method would inevitably deteriorate the performance of ETL. In contrast, thin films prepared by chemical bath deposition (CBD) could significantly restrain the little cracks. Here, SnO 2 ETL are prepared by optimized CBD process, sodium citrate (SC) is explored as an auxiliary reagent to disperse ETL, thus enhances the smoothness and conductivity of the ETL, resulting in a pore‐free flat surface morphology and decreased oxygen vacancy, which is favorable for electron transport and deposition of perovskite (PVK). The PVK film fabricated on the oxygen vacancy free substrate demonstrates high quality and decreased defect density, thus effectively prevents the non‐radiative recombination of carriers. As a result, the short‐circuit current ( J SC ) and open circuit voltage ( V oc ) of the PSC devices have been obviously improved, leading to increased photoelectric conversion efficiency from 21.03% to 22.04%. Meanwhile, the long‐term and moisture stability have been promoted simultaneously.