Ultra-stable, waterproof and self-healing serpentine stretchable conductors based on WPU sheath-wrapped conductive yarn for stretchable interconnects and wearable heaters

Stretchable conductors (SCs) have shown promising potential in the field of stretchable electronic devices for their lightweight, high flexibility, stable performance, and easy integration. However, the conductivity of most reported stretchable conductive composites is sensitive to deformation, and it is still unsatisfactory due to their poor recoverability and low reliability under large strain. In this paper, we have fabricated a serpentine stretchable conductor (SSC) with high conductivity, stretchability, and ultra-stability by spontaneously wrapping elastic waterborne polyurethane (WPU) sheath on the surface of the multi-walled carbon nanotube (MWCNT)/WPU nanocomposite conductive yarn, which was prepared by a simple wet-spinning method. The WPU elastic sheath endows SSC with long-term tensile durability and recoverability. Remarkably, benefiting from the sharing effect of the serpentine structure on the tensile strain energy, SSC shows distinctive strain-insensitive behavior (ΔR/R0 less than 1.6%) up to 100% strain and ultra-high quality factor (Q = 105) at 80% strain. Furthermore, SSC also has temperature resistance, waterproof ability, and self-healing capability, making it capable of being used in harsh circumstances. The combination of high conductivity, stretchability, and super reliability renders many potential applications for SSC, such as stretchable interconnects and wearable heaters. Such serpentine stretchable device with distinctive strain-insensitive behavior provides a novel design idea for stretchy electronics.