光催化
材料科学
硫黄
空位缺陷
制氢
化学工程
光电流
氢
贵金属
纳米颗粒
带隙
金属
催化作用
化学物理
纳米技术
光电子学
化学
结晶学
冶金
有机化学
工程类
生物化学
作者
Jiangwei Shi,Le Yang,Jie Zhang,Zejin Wang,Wenbo Zhu,Ying Wang,Zhigang Zou
标识
DOI:10.1002/chem.202202019
摘要
Abstract Cocatalyst plays an important role in efficient charge transfer and separation for photocatalysis. Herein, a MoS 2 /CdS photocatalyst with MoS 2 as cocatalyst was designed by using Mo‐MOF and Cd‐MOF as precursors. Due to the existence of rich sulfur vacancies and 1T phase, MoS 2 shows strong charge capture and transport ability. The photo‐generated electrons on conduction band (CB) can be bound by the sulfur vacancy of CdS and effectively transported to MoS 2 through the compact interface between the CdS nanoparticles and 2D large‐scale MoS 2 . The optimal photocatalyst 1 %MoS 2 /CdS exhibited dramatically improved photocatalytic hydrogen production activity, which is 28 times that of pristine CdS and even about 2 times that of 1 %Pt/CdS with same loading amount of noble metal Pt. This work highlights the role of Mo‐MOF derived MoS 2 with 1T‐2H phases as a sustainable and prospective candidate of cocatalyst for improving charge separation and photocatalytic stability of MoS 2 /CdS composites.
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