A novel recycling way of blast furnace dust from steelworks: Electrocoagulation coupled micro-electrolysis system in indigo wastewater treatment

In this study, a novel electrocoagulation electrode, based on blast furnace dust (BFD) from steelworks waste, was prepared for indigo wastewater treatment, and the performance was compared with different ratios of Fe-C composite electrodes. The BFD electrode exhibited great electrochemical performance and removal effect. The presence of Fe-C micro-electrolysis in the electrocoagulation system of the BFD electrode was demonstrated by FT-IR, Raman, ESR, and quenching experiments. Density Functional Theory (DFT) calculations further demonstrated that the iron-carbon ratio could influence the degree of O-O breaking and enhance ·OH generation. Finally, the BFD electrode's operating parameters were perfected, and the COD removal and decolorization could reach 75.7% and 95.8% within 60 min, respectively. Fe-C composite electrodes reduce energy consumption compared with the traditional Fe/Al electrode and have a lower production cost, which provides a potential way to recycle and reuse the resources of solid waste in steelworks, the concept of "waste controlled by waste" is realized.