化学
硫系化合物
选择性
铜
催化作用
反应条件
组合化学
有机化学
出处
期刊:Tetrahedron
[Elsevier]
日期:2022-03-01
卷期号:110: 132689-132689
被引量:4
标识
DOI:10.1016/j.tet.2022.132689
摘要
A copper-catalyzed hydroxysulfenylation of alkenes was achieved using disulfides in the presence of n-Bu4NI and H2O. The procedure smoothly proceeded under air atmosphere, and the corresponding β-hydroxysulfides were obtained with regio- and anti-selectivity in good yields. Furthermore, a reaction using diselenides effectively produced the expected β-hydroxyselenides. These reactions could use both chalcogenide groups on dichalcogenides. Further the procedure also worked for hydrosulfenylation using thiols.
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