Ag2Au50(PET)36 Nanocluster: Dimeric Assembly of Au25(PET)18 Enabled by Silver Atoms

Abstract The assembly of atomically precise metal nanoclusters offers exciting opportunities to gain fundamental insights into the hierarchical assembly of nanoparticles. However, it is still challenging to control the assembly of individual nanoclusters at a molecular or atomic level. Herein, we report the dimeric assembly of Au 25 (PET) 18 (PET=2‐phenylethanethiol), where two Au 25 (PET) 18 monomers are bridged together by two Ag atoms to form the Ag 2 Au 50 (PET) 36 dimer. The Ag 2 Au 50 (PET) 36 dimer is a unique mesomer, which has not been found in any other chiral metal nanoclusters. Furthermore, the Ag 2 Au 50 (PET) 36 dimer is distinct from the Au 25 (PET) 18 monomer in its optical, electronic, and catalytic properties. This study is expected to provide a feasible strategy to precisely modulate the assembly of metal nanoclusters with controllable structures and properties.