巯基乙酸
检出限
化学
胶体金
热重分析
傅里叶变换红外光谱
核化学
动态光散射
色谱法
毒死蜱
纳米颗粒
杀虫剂
材料科学
有机化学
化学工程
纳米技术
生物
工程类
农学
作者
Hongwei Zhang,Yuan Qi,Yanchao Zhang,Yumei Yan,Haixiang Gao
出处
期刊:Analytical Methods
[The Royal Society of Chemistry]
日期:2022-01-01
卷期号:14 (20): 1996-2002
被引量:7
摘要
Herein, we report the preparation of a gold nanoparticle-thioglycolic acid (TGA@AuNP) suspension for the label-free colorimetric detection of the organophosphorus pesticide chlorpyrifos. This colorimetric sensor was synthesized by a one-pot method, providing thioglycolic acid (TGA)-modified gold nanoparticles with a negatively charged surface. The formation of TGA@AuNPs was confirmed by Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and dynamic light scattering (DLS). In addition, chlorpyrifos was quantitatively determined by UV-vis spectrophotometry. The modification time, TGA concentration, pH, incubation time, temperature, ionic strength, and interference of other pesticides were also investigated. The synthesized TGA@AuNP colorimetric sensor possesses a detection limit as low as 20 μg L-1 and a selective sensing response, and the detection time is less than 2 minutes. In addition, this method can also be applied to detect various practical samples in life, such as environmental water samples and tea.
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