Highly Stable Graphene‐Based Flexible Hybrid Transparent Conductive Electrodes for Organic Solar Cells

Abstract Flexible transparent conductive electrodes (TCEs) are an essential part of flexible electronic and energy devices. As a promising alternative to ITO (In 2 O 3 :Sn), silver nanowire has poor environmental stability and adhesion, which limits its development. Herein, transition metal carbides and carbonitrides called MXene are inserted between silver nanowires and graphene grown by chemical vapor deposition to improve the conductivity, adhesion, roughness, and stability of the electrode. Nanosheets fill the voids of the network and connect the nanowires with graphene to provide more conductive channels. In addition, due to the solvent evaporation effect and thermal effect in the preparation process, the nanowire junctions are welded together. Based on the unique structure, the proposed composite TCE shows low sheet resistance (18.1 Ω sq −1 ) and high optical transmittance (88.1% at 550 nm). Furthermore, compared to the reference samples, the composite TCEs demonstrate stable electrical performances under different environmental conditions, including thermal environment, exposures to air for 80 days, and bending for 2000 cycles. Finally, flexible organic solar cells (OSCs) are prepared using the composite TCEs, which show comparable efficiency to that of ITO‐based OSCs. Therefore, the flexible transparent electrodes are expected to be applied in solar cells, organic light‐emitting diodes, and a broader range.