Novel Oxidative Membrane Reactor for Dehydrogenation Reactions
作者
Renni Zhao,Naotsugu Itoh,Rakesh Govind
出处
期刊:Acs Symposium Series [American Chemical Society] 日期:1990-09-21卷期号:: 216-230被引量:8
标识
DOI:10.1021/bk-1990-0437.ch020
摘要
The use of a membrane reactor for shifting equilibrium controlled dehydrogenation reactions results in increased conversion, lower reaction temperatures and fewer by-products. Results will be presented on a palladium membrane reactor system for dehydrogenation of 1-butene to butadiene, with oxidation of permeating hydrogen to water on the permeation side. The heat released by the exothermic oxidation reaction is utilized for the endothermic dehydrogenation reaction.