Y2(CO3)3·H2O and (NH4)2Ca2Y4(CO3)9·H2O: Partial Aliovalent Cation Substitution Enabling Evolution from Centrosymmetry to Noncentrosymmetry for Nonlinear Optical Response

An effective approach, the partial aliovalent cation substitution (PACS), was successfully employed to develop nonlinear optical (NLO) material. Two novel rare earth carbonates, Y 2 (CO 3 ) 3 ·H 2 O (YC) and (NH 4 ) 2 Ca 2 Y 4 (CO 3 ) 9 ·H 2 O (CYC), were synthesized, which feature the same honeycomb-like framework structure. From YC to CYC, the partial substitution of Y 3+ with Ca 2+ led to the evolution of space group from centrosymmetric P 6 3 / mcm to noncentrosymmetric P 6 3 mc. The CYC exhibited a second harmonic generation (SHG) effect of 2.1 × KH 2 PO 4 (KDP) and a deep-UV cutoff edge (<200 nm). It was concluded that the SHG effect originates from the ordered arrangement of (CO 3 ) 2– groups and the dipole polarization enhancement of [Ca 0.33 Y 0.67 O 9 ] polyhedra. Specifically, the long-range ordered electric field of channels induced the ordered arrangement of (CO 3 ) 2– groups. This synthetic approach and SHG-activated induction mechanism may afford new strategies for the design and synthesis of NLO materials.