), an ultrahigh fine particle capture efficiency of 99.999% (N100 level for masks), and can allow the antibacterial efficacy and air filtration performance to be renewed in a one-step chlorination process, which has never been reported before. More importantly, for the first time, we revealed the synergistic effect involving the intrinsic structure of polymers and the assembling structure of nanofibers on the chlorination capacity. The successful fabrication of such a fascinating membrane can provide new insights into the development of nanofibrous materials in a multifunctional, durable, and renewable form.