电解质
电池(电)
氢
材料科学
流量(数学)
核工程
体积流量
电极
机械
热力学
冶金
化学
工程类
物理
物理化学
功率(物理)
有机化学
作者
Steven Selverston,Enoch A. Nagelli,Jesse S. Wainright,Robert F. Savinell
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2019-01-01
卷期号:166 (10): A1725-A1731
被引量:27
摘要
Principles of sealed iron flow batteries are introduced and a semi-empirical model that incorporates the hydrogen evolution reaction and electrolyte rebalancing is developed. Hydrogen generation rates are measured using pressure measurements in sealed vessels. Electrolyte dynamics with and without electrolyte rebalancing are simulated and discussed, and a good agreement is found between measured and simulated pressure responses. The sealed battery system with in-tank rebalancing demonstrates stable operation at low hydrogen partial pressure during 10 days and 100 cycles at ± 100 mA cm−2 at room temperature.
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