化学
光漂白
生物相容性
量子产额
发光
聚乙烯醇
马来酸
共轭体系
碳纤维
吸收(声学)
富马酸
光化学
荧光
核化学
有机化学
复合数
材料科学
聚合物
共聚物
物理
复合材料
量子力学
光电子学
作者
Huang Tang,Yuran Tang,He Zhu,Man Xiao,Mingming Guo
标识
DOI:10.1016/j.molstruc.2021.132034
摘要
Carbon dots (CDs) have a wide application prospect in biomedical, fluorescent probes and other fields due to their abundant advantages, such as excellent optical properties, low toxicity, etc... In this essay, carbon dots with nitrogen-doped (MA-CDs) carrying good biocompatibility and relatively high absolute fluorescence quantum yield (12.37%) was prepared by microwave synthesis using maleic acid with good conjugated structure as carbon precursor and arginine with the highest content of nitrogen in amino acids as nitrogen source. The UV-vis absorption spectra and time-resolved spectra show that it has dual light centers, and the luminescence center 2 has a long fluorescence lifetime (25.7602 ns). In addition, MA-CDs has excellent water solubility, good photobleaching resistance, and good stability in physiological environment. Based on this, we successfully prepared MA-CDs and polyvinyl alcohol (PVA) composite films and constructed iron ion fluorescence probes with wide linear range.
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