膜
硅烷
单体
化学工程
热稳定性
硅醇
化学
环氧树脂
阳离子聚合
材料科学
水解
高分子化学
共聚物
水溶液
聚合物
有机化学
生物化学
工程类
催化作用
作者
Dian Zhang,Masakoto Kanezashi,Toshinori Tsuru,Kazuki Yamamoto,Takahiro Gunji,Yoshinori Adachi,Joji Ohshita
标识
DOI:10.1016/j.memsci.2021.120162
摘要
Epoxy-based reverse osmosis (RO) membranes with an organically bridged polysilsesquioxane (PSQ) skeleton were prepared by a sol-gel process that involved the copolymerization of bis[3-(triethoxysilyl)propyl]amine (BTESPA) and triethoxy(3-glycidyloxypropyl)silane (TEGPS). RO experiments using 2000 ppm NaCl aqueous solution indicated that the use of epoxy-containing monomer TEGPS significantly improved performance, yielding water permeability of 1 × 10−12 m3/m2sPa and salt rejection of 98%, approximately. This is likely because of the ring opening of the epoxy units, which leads to the formation of hydroxy (C–OH) groups during sol formation. Some C–OH groups underwent condensation with silanol to generate C–O–Si bonds in the gelation process. Immersion of the resultant membrane in water resulted in the hydrolysis of C–O–Si bonds to re-generate C–OH units. This increased membrane hydrophilicity and further improved permeability, although salt rejection slightly decreased. It was also found that membranes derived from TEGPS showed high resistance to chlorine and thermal stability.
科研通智能强力驱动
Strongly Powered by AbleSci AI