Low temperature energy- efficient synthesis methods for bismuth-based nanostructured photocatalysts for environmental remediation application: A review

Bismuth-based composite materials have unique structural, chemical, optical, and electrical properties that are highly beneficial in Photocatalysis. The layered structure and tunable bandgap properties of the Bismuth-based composites are advantageous for the absorption of solar light efficiently. Also, these properties help the separation and recombination of photogenerated charge carriers, leading to enhancement in the photocatalytic activity. Synthesis of the catalyst at a lower temperature to produce catalyst reduces the production cost and electrical energy consumption. This review provides an overview of the recent development in Bismuth-based composite nanostructured photocatalytic materials, mainly using low-temperature driven synthesis methods. Herein, we have mainly summarized the primarily used low temperature-based synthetic routes, particularly in the temperature range of 50-300 °C for synthesizing Bismuth-based composite materials. In addition to this, the photocatalytic mechanism, the textural, structural, electronic, and photocatalytic properties of the synthesized photocatalysts are discussed. The literature shows that the surface area of the composite Bismuth-based photocatalytic materials synthesized using the low-temperature synthetic route is in the range of 1.5-81 m2/g and can be activated by solar, ultraviolet, and Light Emitting Diode (LEDs) light irradiation based on the synthetic route. Their photocatalytic performance and structural stability are excellent and utilized for several runs. The comprehensive understanding of the low-temperature synthesis of Bismuth-based composite materials for visible light-activated photocatalytic applications provided will be useful for developing photocatalytic materials on an industrial scale due to energy-efficient synthetic routes. Furthermore, the prospects of low temperature-driven Bismuth-based composite synthesis routes are discussed.