退火(玻璃)
工作职能
能量转换效率
工作(物理)
材料科学
电子
有机太阳能电池
电子迁移率
化学工程
电子传输链
光电子学
图层(电子)
纳米技术
化学
物理
聚合物
热力学
冶金
复合材料
工程类
量子力学
生物化学
作者
Chih-Yung Huang,Shengwei Shi,Huangzhong Yu
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2021-09-08
卷期号:6 (10): 3464-3472
被引量:49
标识
DOI:10.1021/acsenergylett.1c01656
摘要
The Nb2CTx nanoflakes as members of the MXene family have attracted a lot of attention because of their unique optoelectronic properties. In this work, we use alkali and annealing treatments to regulate the surface functional groups in Nb2CTx and then adjust its work function (WF). After KOH treatment, the −F group is replaced by an −OH group, leading to a decrease in WF from 4.62 eV (Nb2CO1.2OH0.6F0.2) to 4.32 eV (Nb2CO1.2OH0.8). After annealing, −OH is transformed into −O, resulting in a WF increase to 5.03 eV (Nb2CO1.36OH0.2). Polymer solar cells (PSCs) based on PM6:BTP-eC9:PC71BM with tuned Nb2CTx as the electron transport layer (ETL) and the hole transport layer (HTL) exhibit the highest power conversion efficiency (PCE) of 17.64% and 17.51%, respectively. These efficiencies are comparable to those gained using conventional charge transport layers. This work provides a good method to tune the WF of Nb2CTx and exhibits the Nb2CTx nanoflakes have a great application prospect in PSCs.
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