丙烯酸酯
甲基丙烯酸酯
润湿
材料科学
阳极
电解质
聚合物
硅
丙烯酸
复合材料
微粒
工程类
化学工程
聚合
共聚物
化学
电极
冶金
物理化学
作者
Zhixin Xu,Jun Yang,Tao Zhang,Yanna Nuli,Jiulin Wang,Shin‐ichi Hirano
出处
期刊:Joule
[Elsevier]
日期:2018-05-01
卷期号:2 (5): 950-961
被引量:305
标识
DOI:10.1016/j.joule.2018.02.012
摘要
Si has been regarded as a promising anode material for Li-ion batteries. However, its dramatic volume change during cycling poses formidable challenges to building stable electrodes. Since Si microparticles (SiMPs) can easily cause the pulverization and loss of electronic contact, many previous works were focused on porous-structured, nanostructured, or hierarchically structured silicon materials to improve the cycle stability. However, their low-cost and mass production is mostly difficult or even impossible. Herein, a water-soluble polymer binder, poly(acrylic acid)-poly(2-hydroxyethyl acrylate-co-dopamine methacrylate), is designed and synthesized. It shows better wettability to liquid electrolyte than poly(acrylic acid). Moreover, its multiple network structure with rigid-soft chains and bonds, and special self-healing capability in situ formed during the electrode preparation, not only provides enough mechanical support but also buffers the strain caused by the volume change of SiMPs. Thus, the cycle stability and rate performance are remarkably improved under high reversible capacity or electrode loading.
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