催化作用
化学工程
能源消耗
化学
消费(社会学)
环境科学
材料科学
纳米技术
有机化学
社会科学
电气工程
工程类
社会学
作者
Qinghua Lai,Sam Toan,Mohammed A. Assiri,Huaigang Cheng,Armistead G. Russell,Hertanto Adidharma,Maciej Radosz,Maohong Fan
标识
DOI:10.1038/s41467-018-05145-0
摘要
Abstract Implementing Paris Climate Accord is inhibited by the high energy consumption of the state-of-the-art CO 2 capture technologies due to the notoriously slow kinetics in CO 2 desorption step of CO 2 capture. To address the challenge, here we report that nanostructured TiO(OH) 2 as a catalyst is capable of drastically increasing the rates of CO 2 desorption from spent monoethanolamine (MEA) by over 4500%. This discovery makes CO 2 capture successful at much lower temperatures, which not only dramatically reduces energy consumption but also amine losses and prevents emission of carcinogenic amine-decomposition byproducts. The catalytic effect of TiO(OH) 2 is observed with Raman characterization. The stabilities of the catalyst and MEA are confirmed with 50 cyclic CO 2 sorption and sorption. A possible mechanism is proposed for the TiO(OH) 2 -catalyzed CO 2 capture. TiO(OH) 2 could be a key to the future success of Paris Climat e Accord.
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