Preparation of poly(aspartic acid) superabsorbent hydrogels by solvent-free processes

Abstract Poly(aspartic acid) (PASP) hydrogel is a biodegradable and biocompatible polymer with high water absorbing ability. Traditionally, the production of PASP hydrogel consumes large amounts of organic solvents, i.e., dimethylformamide (DMF) or dimethyl sulfoxide (DMSO). This traditional approach is now considered costly, complex and environmentally unfriendly due to required used solvent disposal. The present research explores two novel methods in preparing PASP hydrogel without organic solvent, by using hydrazine hydrate and ethylene glycol diglycidyl ether (EGDGE) or poly(ethylene glycol) diglycidyl ether (PEGDGE) as the cross-linkers. Absorbent ability and other characteristics are determined. Preparing PASP hydrogel in aqueous solution is promising and finds its use in many applications.