Improving energy efficiency in buildings is critical for supporting sustainable growth in the construction sector. In this context, the implementation of passive solar solutions in the building envelope plays an important role. Trombe wall is a passive solar system that presents great potential for passive solar heating purposes. However, its performance can be enhanced when the Internet of Things is applied. This study employs a multi-domain smart system based on Matter-enabled IoT technology for maximizing Trombe wall functionality using appropriate 3D-printed ventilation grids. The system includes ESP32-C6 microcontrollers with temperature sensors and ventilation grids controlled by actuated servo motors. The system is automated with a Raspberry Pi 5 running Home Assistant OS with Matter Server. The integration of the Matter protocol provides end-to-end interoperability and secure communication, avoiding traditional systems based on MQTT. This work demonstrates the technical feasibility of implementing smart ventilation control for Trombe walls using a Matter-enabled infrastructure. The system proves to be capable of executing real-time vent management based on predefined temperature thresholds. This setup lays the foundation for scalable and interoperable thermal automation in passive solar systems, paving the way for future optimizations and addicional implementations, namely in order to improve indoor thermal comfort in smart and more efficient buildings.