Fast Self-Healing Superhydrophobic Thermal Energy Storage Coatings Fabricated by Bio-Based Beeswax and Artificially Cultivated Diatom Frustules

Diatom frustules (DFs) with delicate hierarchical pores and a large specific surface area are extracted from artificially cultured diatoms, showing their utilization potential as shape-stabilized phase change materials (ss-PCMs). Herein, we successfully prepared a fully biomass-based ss-PCM, superhydrophobic thermal energy storage (STES) coating by employing beeswax (BW) as phase change materials (PCMs) and DFs as supporting materials via a facile spraying method. DFs can adsorb as much as 65 wt % BW without leakage, accompanied with a high heat storage capacity of 112.57 J/g. The thermal stability test demonstrates that the DF/BW coating can undergo 500 heating-freezing cycles with the reduction of the phase change enthalpy being less than 5%. Simultaneously, the DF also endows BW with a higher thermal degradation temperature (from ∼200 to ∼250 °C). In addition, the DF/BW coating shows superhydrophobicity due to the incorporation of the low surface energy of BW and the micro/nanostructures of DFs. This superhydrophobic surface can quickly and repeatedly recover its excellent water repellency through a simple heat treatment (80 °C, 20 min) after being damaged by a water impact or strong acid and alkali corrosion. This self-healing ability can effectively overcome the poor durability of traditional superhydrophobic materials. Our research can expand the application of DFs in the field of ss-PCMs and guide the preparation of durable superhydrophobic surfaces with rapid self-healing performance.