化学
分子内力
立体选择性
紫杉烷
三环
立体化学
Diels-Alder反应
有机化学
催化作用
医学
内科学
癌症
乳腺癌
作者
Randy W. Jackson,Kenneth J. Shea
标识
DOI:10.1016/s0040-4039(00)76206-x
摘要
A highly functionalized type 2 intramolecular Diels-Alder precursor, suited for use in the synthesis of taxane natural products, has been prepared. Its stereoselective preparation and cyclization to an epi-tricyclic taxane intermediate are described.
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