A Hierarchical Metal–Organic Framework Intensifying ROS Catalytic Activity and Bacterial Entrapment for Engineering Self‐Antimicrobial Mask

. Additionally, the dendritic and negative-charged surface engineered in this Ce-MOF substantially enhances the binding affinity toward positive-charged bacteria, enabling the spatial proximity between the bacteria and the short-lived ROS and therefore maximizing the utilization of highly toxic ROS to inactivate bacteria. It is demonstrated that this Ce-MOF-integrated face mask displays almost 100% antimicrobial efficacy even in insufficient light and dark scenarios. This work provides important insights into the design of antibacterial MOF materials by a pore- and surface-engineering strategy and sheds new light on the development of advanced self-antimicrobial devices.