4D printing of fiber-reinforced auxetic structures: the building blocks: A review

Abstract Four-dimensional (4D) printing has recently received much attention in the field of smart materials. It concerns using additive manufacturing to obtain geometries that can change shape under the effect of different stimuli. Such a technique enables the fabrication of 3D printed parts with the additional functionality of scalable, programmable, and controllable part shapes over time. 
This review provides a comprehensive examination of advances in the field of 4D printing, emphasizing the integration of fiber reinforcement and auxetic structures as crucial building blocks. 
The incorporation of fibers enhances structural integrity, while auxetic design principles contribute unique mechanical properties, such as negative Poisson's ratio and great potential for energy absorption due to their specific deformation mechanisms. Therefore, they present potential applications in aerospace, drones, and robotics.
The objective of this review article is first to describe the distinctive properties of shape memory polymers (SMPs), auxetic structures, and composite (fiber-reinforced) materials. A review of applications that use combinations of such materials is also presented when appropriate. The goal is to get a grip on the delicate balance between the different properties achievable in each case. The paper concludes by describing recent advances in 4D printing of fiber-reinforced auxetic structures.