量子级联激光器
级联
激光器
吸收(声学)
校准
波长
检出限
分析化学(期刊)
红外线的
吸收光谱法
化学
材料科学
光学
光电子学
物理
色谱法
量子力学
作者
Kun Duan,Daxin Wen,Yongbin Ji,Ke Xu,Zebo Huang,Xiang Zhang,Shunchun Yao,Wei Ren
标识
DOI:10.1016/j.saa.2024.123864
摘要
We report a mid-infrared quantum cascade laser absorption sensor capable of measuring SO2 and SO3 simultaneously and sensitively at elevated temperatures. In the sensor development, the intense transitions of SO2 and SO3 in the mid-infrared region of 1129 cm-1 and 1398 cm-1 were exploited by two quantum cascade lasers. A high-temperature multipass cell was adopted to increase the absorption path length to 10 m. The quantitative concentrations of SOx were directly obtained from the calibration-free wavelength modulation spectroscopic method, which was validated at varied temperature and pressure conditions. From Allan deviation analysis, we achieved a minimum detection limit of 8 parts per billion (ppb) for SO2 and 3 ppb for SO3, with an average time of 100 s. Lastly, we successfully demonstrated the real-time and sensitive measurement of SO2 and SO3 during the oxidation reaction of SO2 by O3 at 460 K. Our laser sensor shows great potential for in-situ and real-time monitoring of SOx from combustion emissions.
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