Carrier Dynamics of Efficient Triplet Harvesting in AgBiS2/Pentacene Singlet Fission Solar Cells

Abstract Singlet fission is a process by which an organic semiconductor is able to generate two triplet excitons from a single photon. If charges from the triplets can be successfully harvested without heavy losses in energy, then this process can enable a single‐junction solar cell to surpass the Shockley–Queisser limit. While singlet fission processes are commonly observed in several materials, harvesting the resulting triplets is difficult and has been demonstrated with only a few transport materials. Here, transient absorption spectroscopy is used to investigate singlet fission and carrier transfer processes at the AgBiS 2 /pentacene (AgBiS 2 /Pc) heterojunction. The successful transfer of triplets from pentacene to AgBiS 2 and the transfer of holes from AgBiS 2 to pentacene is observed. Further singlet fission in pentacene by modifying the crystallinity of the pentacene layer and have fabricated the first singlet fission AgBiS 2 /Pc solar cell is enhanced. Singlet fission devices exhibit higher external quantum efficiency compared with the control devices, and thus demonstrating the significant contribution of charges from the singlet fission process.