金属有机骨架
连续流动
微波食品加热
水准点(测量)
产量(工程)
材料科学
工艺工程
有机合成
微波辐射
生产(经济)
比例(比率)
化学计量学
流量(数学)
纳米技术
计算机科学
生化工程
化学
冶金
有机化学
催化作用
机械
工程类
物理
电信
经济
地理
吸附
宏观经济学
量子力学
大地测量学
作者
Marco Taddei,Daniel Antti Steitz,Jeroen A. van Bokhoven,Marco Ranocchiari
标识
DOI:10.1002/chem.201505139
摘要
Abstract Metal–organic frameworks are having a tremendous impact on novel strategic applications, with prospective employment in industrially relevant processes. The development of such processes is strictly dependent on the ability to generate materials with high yield efficiency and production rate. We report a versatile and highly efficient method for synthesis of metal–organic frameworks in large quantities using continuous flow processing under microwave irradiation. Benchmark materials such as UiO‐66, MIL‐53(Al), and HKUST‐1 were obtained with remarkable mass, space–time yields, and often using stoichiometric amounts of reactants. In the case of UiO‐66 and MIL‐53(Al), we attained unprecedented space–time yields far greater than those reported previously. All of the syntheses were successfully extended to multi‐gram high quality products in a matter of minutes, proving the effectiveness of continuous flow microwave technology for the large scale production of metal–organic frameworks.
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